Bis(2-benzoyl-1-phenylethenolato-κ2 O,O′)(ethanol-κO)dioxidouranium(VI)
نویسندگان
چکیده
In the title compound, [U(C(15)H(11)O(2))(2)O(2)(C(2)H(6)O)], the U(VI )atom has a penta-gonal-bipyramidal coordination geometry. The two so-called '-yl' O atoms occupy the axial positions whereas four O atoms from the two chelating dibenzoyl-methanate ligands and the O atom from the ethanol mol-ecule are situated in the equatorial plane. Inter-molecular hydrogen bonds between one of the '-yl' O atoms and the ethanol OH group assemble mol-ecules into a centrosymmetric dimer.
منابع مشابه
Bis(4-benzoyl-3-methyl-1-phenyl-4,5-dihydro-1H-pyrazol-5-olato-κ2 O,O′)(methanol-κO)dioxidouranium(VI) methanol monosolvate
In the title compound, [U(C(17)H(13)N(2)O(2))(2)O(2)(CH(3)OH)]·CH(3)OH, the U(VI) ion is coordinated by seven O atoms in a distorted pentagonal-bipyramidal geometry with two 3-methyl-1-phenyl-4-benzoyl-4,5-dihydro-1H-pyrazol-5-olate groups with two O atoms in a bidentate chelating coordination mode and by three O atoms, one of which is from a methanol ligand. The crystal packing can be describe...
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متن کاملtrans-Bis(2-benzoylbenzoato-κO 1)bis(ethanol-κO)bis(1H-imidazole-κN 3)nickel(II)
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007